White Lead

(flake white, cremnitz white, kerms white, Berlin white, silver white, slate white)

Origin, History and Characteristics

Prepared artificially since the earliest historical times and used until the nineteenth century, this warm  white is very opaque, has outstanding  brushing qualities and mixes well with every color on the artist's palette. As the name lead white suggests, it is a by-product of lead, and whatever the form of manufacture used, the purity of the color depends on the purity of the lead. Purifying processes greatly increase the cost of the product. White lead has always been one of the most important pigments in many painting techniques.

Its importance has been immeasurable, and is the only material that has been consistently used from ancient times until the present. The monopoly in lead white production was not broken until the nineteenth century, when zinc oxide became a competitor, and in the twentieth century, it has been almost completely replaced by titanium dioxide, which is superior to lead in some properties, and unlike zinc oxide, has the strong covering ability that lead white possesses. Since white in painting is the equivalent of light in nature, it has been essential to every aspect of painting: from flesh to skies, and so on.

In the Dutch and Old German process strips of lead rolled up into spirals were placed in closed earthenware jars containing acetic acid, and then pots were hen buried under tanner's bark or dung; the heat evolved by fermentation aids in the formation of white lead through an increase of carbonic acid. Very soon a thin coat of white coating forms. The white lead is then washed of and cleaned. White lead is extremely poisonous and must be handled with care.

White Lead in Vermeer's Painting

White has always played an important part in the art and craft of painting. The great part of pigments on a progressive scale of gray would fall into the medium dark to dark category. Only lead-tin yellow is by itself light pigment. In order to portray the light areas which are for indispensable to convey the sense of natural illumination, white must be added to heighten most of the darker pigments.

Vermeer, as all other painters of the time, used it extensively to lighten other colors and as the principle component used to depict the characteristic white-washed walls (see right below) seen in so many of his paintings. Vermeer was also aware that the rendering of surface textures enhances the visual significance of various material realities he portrayed.

A grainy texture can be seen on the surface of many of the lightest areas are cause d by aggregates of white-lead particles. These  lumpy aggregates that can "found in Vermeer's paintings have also been noted in several Frans Hal's paintings and are typical for the stack process of white lead production for which Holland was famous in the seventeenth century. "¹ "This coarseness was not considered to be a defect. Since white lead was the principle component of strongly lit areas of the artist's composition, the roughness of the paint layer accentuated the optical effect brightness by catching light unevenly and producing a sparkling effect."²