Indigo
Origin, History and Characteristics
Indigo was probably used as a painting pigment by ancient Greeks and Romans. Marco Polo (13th century) was the first to report on the preparation of indigo in India. The Indiagofera tinctoria plant thrives in a tropical climate; the active ingredient is found in the leaves. Aniline blue has the same chemical composition and replaced it in 1870. Indigo does not hold up in an oil base.
To prepare the dye, freshly cut plants are soaked until soft, packed into vats and left to ferment. It is then pressed into cakes for use as a watercolor or dried and ground into a fine powder for use as an oil paint. Bound with oil it is very transparent making it a good pigment for glazing. It has a strong yellow undertone. It has fair tinting strength and may fade rapidly when exposed to strong sunlight. Indigo has been used by artists and clothes manufacturing.
Indigo in Vermeer's Painting
Vermeer is known to have used indigo in only two works. It can be found in an admixture with smalt and in the deep blue robe of the seated Christ in Christ in the House of Martha and Mary. This is the only deep blue color in Vermeer's oeuvre where natural ultramarine cannot be found.
The presence of indigo was recently detected with weld in a deep green glaze which covered the dark tone of the background of the Girl with a Pearl Earring. This glaze has almost entirely degraded. It was originally a smooth, glossy, translucent green made to give depth and the precious quality of enamel to the background.
How to Paint Your Own Vermeer: Materials & Methods of a Seventeenth-Century Master
by Jonathan Janson

the book
How to Paint Your Own Vermeer is a straightforward, practical guide on how to reproduce Vermeer's day-to-day painting procedures for today's discerning artist.
the CD-rom
Following the guidlines in the book, a hypothetical Vermeer can be viewed in a series of 180 sequential digital images as it progresses step-by-step from the stretching of the canvas to the final touches and glazes.
a detail of Vermeer's Christ in the House of Martha and Mary